{"id":3198,"date":"2016-06-06T10:58:25","date_gmt":"2016-06-06T15:58:25","guid":{"rendered":"https:\/\/advancedplatingtech.com\/?p=3198"},"modified":"2024-11-25T08:45:16","modified_gmt":"2024-11-25T14:45:16","slug":"corrosion-protection-benefits-electroless-nickel-plating","status":"publish","type":"post","link":"https:\/\/advancedplatingtech.com\/blog\/corrosion-protection-benefits-electroless-nickel-plating\/","title":{"rendered":"Corrosion Protection Benefits of Electroless Nickel Plating"},"content":{"rendered":"<h2><a href=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2017\/12\/APT-Blog.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-7245 size-full\" src=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2017\/12\/APT-Blog.png\" alt=\"\" width=\"1920\" height=\"480\" srcset=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2017\/12\/APT-Blog.png 1920w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2017\/12\/APT-Blog-300x75.png 300w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2017\/12\/APT-Blog-1024x256.png 1024w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2017\/12\/APT-Blog-768x192.png 768w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2017\/12\/APT-Blog-1536x384.png 1536w\" sizes=\"(max-width: 1920px) 100vw, 1920px\" \/><\/a><\/h2>\n<h2><strong>Electroless Nickel Plating: Superior Corrosion\u00a0Protection<\/strong><\/h2>\n<p>&nbsp;<\/p>\n<p><a href=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignright wp-image-6017 size-medium\" src=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-1-300x200.png\" alt=\"Electroless Nickel over Stainless Steel\" width=\"300\" height=\"200\" srcset=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-1-300x200.png 300w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-1-1024x683.png 1024w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-1-768x512.png 768w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-1-1536x1024.png 1536w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-1.png 2048w\" sizes=\"(max-width: 300px) 100vw, 300px\" \/><\/a><\/p>\n<p style=\"text-align: left;\">Raw metals other than precious metals can easily oxidize and corrode over time when exposed to various environmental conditions and corrosive applications.\u00a0 The proper design of any component must begin with a surface engineering evaluation to ensure that the product will function reliably over the intended service life.\u00a0 Even in relatively mild service applications, corrosion can result in functional issues and shortfalls.\u00a0 Electroless nickel plating can provide a robust solution to corrosive attack across a range of corrosive mechanisms\u00a0including\u00a0galvanic corrosion, chemical attack and erosion. <a href=\"https:\/\/advancedplatingtech.com\/electroless-nickel\/electroless-nickel-plating\/\">Electroless nickel plating<\/a> (EN) can be applied to a wide range of basis metals including steel, copper, brass and aluminum alloys. Electroless Nickel plating is currently utilized to promote corrosion protection performance across a diverse range of industries including heavy equipment, oil &amp; gas, power transmission &amp; distribution, automotive, marine and railway to name a few.<!--more--><\/p>\n<h2><span style=\"text-decoration: underline;\"><strong><em>Electroless Nickel Plating Characteristics<\/em><\/strong><\/span><\/h2>\n<p>EN is different from electrolytic nickel plating in that is does not require an external source of electrons for deposition. This auto-catalytic process does not need to pass electric current through parts to form the plated deposit which gives the EN deposit greatly improved uniformity over that of electrolytic deposits. \u00a0The improved uniformity of ENP\u00a0is a principle deposit property that enhances corrosion resistance on all features of a part especially in features that are traditionally difficult to coat such as thru holes or counter bores. \u00a0Another unique characteristic of ENP\u00a0is that the nickel co-deposits phosphorus of varying amounts from 4-13% based on the bath type. The level of phosphorus directly impacts key deposit properties such as hardness, corrosion resistance and ductility. \u00a0In addition, post-plate heat treatment can be used to alter the structure of the electroless nickel plating thereby increasing hardness to as high as 70 Rc.<\/p>\n<p><strong><em><span style=\"text-decoration: underline;\">Advanced Electroless Nickel Plating Options<\/span><a href=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignright wp-image-6019\" src=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-2-300x200.png\" alt=\"Electroless Nickel Plating Corrosion Protection\" width=\"339\" height=\"226\" srcset=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-2-300x200.png 300w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-2.png 697w\" sizes=\"(max-width: 339px) 100vw, 339px\" \/><\/a><\/em><\/strong><\/p>\n<p>Advanced Plating Technologies has developed processes to further enhance the corrosion performance of electroless nickel plating by utilizing a multi-layer or duplex systems consisting of an underplate of copper and\/or electrolytic nickel prior to the electroless nickel deposit.\u00a0 APT also offers proprietary sealing technologies such as\u00a0our H4 and H5 molecular sealers that can increase the salt spray performance of ENP\u00a0by as much as 2x.<\/p>\n<h2><strong><em><u>Types of Electroless Nickel Plating &#8211; Corrosion Protection Options<\/u><\/em><\/strong><\/h2>\n<p>Traditional electroless nickel phosphorus plating is broken down into three specific groups, 1) low phosphorus (&lt;5% P), medium phosphorus (6-10% P) and high phosphorus (11-13% P).\u00a0 Depending upon design considerations and the corrosion performance required, the phosphorus level and deposit thickness can be adjusted accordingly. Advanced Plating Technologies offers both medium phosphorus electroless nickel plating and high phosphorus ENP. A breakdown of each EN type is provided below:<\/p>\n<ul>\n<li><em>High Phosphorus (11-13% P)<\/em>: High phosphorus electroless nickel plating (high-phos) provides the greatest corrosion resistance, is non-magnetic, has the lowest melting point (~ 880C) and<a href=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/phosph.-Info-Graphic.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignright wp-image-6383\" src=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/phosph.-Info-Graphic-120x300.png\" alt=\"\" width=\"240\" height=\"600\" srcset=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/phosph.-Info-Graphic-120x300.png 120w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/phosph.-Info-Graphic-410x1024.png 410w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/phosph.-Info-Graphic-768x1920.png 768w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/phosph.-Info-Graphic-614x1536.png 614w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/phosph.-Info-Graphic.png 800w\" sizes=\"(max-width: 240px) 100vw, 240px\" \/><\/a> is the most ductile of the EN deposits. As-plated the deposit has an amorphous structure with a hardness between 48-55 Rc that can be increased to 66-70 Rc with post-plate heat treatment. Due to the amorphous structure, high phosphorus electroless nickel has the lowest as-plated internal stress making it the best electroless nickel for heavy build deposits capable of being plated to thicknesses of up to 0.005 inches per side.\u00a0 The deposit tends to have a semi-bright appearance that will vary based upon the raw surface finish of the plated part.\u00a0 High phosphorus electroless nickel has a slower plating rate as compared to medium phosphorus electroless nickel which can increase cost.<\/li>\n<li><em>Medium Phosphorus (6-10% P)<\/em>:\u00a0 Medium phosphorus electroless nickel (mid-phos) is often referred to as the \u201cwork horse\u201d electroless nickel.\u00a0 It provides good corrosion resistance, solderability and a higher melting point (~1000 C).\u00a0 Mid-phos electroless nickel plates in a mixed amorphous\/micro crystalline state and has a hardness of 58-62 Rc as plated and can be increased to 66-70 Rc with post-plate heat treatment options.\u00a0 Medium phosphorus electroless nickel plating has a semi-bright to bright appearance that will vary based on the raw surface finish of the part.\u00a0 A common advantage to using mid-phosphorus EN plating is the faster plating\u00a0rate which can reduce cost over high-phos EN.<\/li>\n<li><em>Low Phosphorus (5% or less P)<\/em>: A low-phosphorus electroless nickel plating (low-phos) provides the highest as-plated hardness (up to 60 Rc) and is the least ductile due to the micro-crystalline as-plated structure. Low-phos is also the least corrosion resistant of the three electroless nickel types but is the most conductive and solderable in the as-plated state.\u00a0 Fewer metal finishing job shops offer low phosphorus electroless nickel plating since there is typically a much higher commercial demand for medium or high phosphorus varieties.<\/li>\n<\/ul>\n<p>APT has compiled a summary Technical Data Sheet to provide a simple one-sheet reference on the various properties of electroless nickel plating.\u00a0 Select on the image below to view, print or save this reference.<\/p>\n<p><a href=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/Tech-Data-Sheet.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-large wp-image-3215\" src=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/Tech-Data-Sheet-1024x790.jpg\" alt=\"Electroless Nickel Technical Data Sheet\" width=\"640\" height=\"494\" srcset=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/Tech-Data-Sheet-1024x790.jpg 1024w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/Tech-Data-Sheet-300x231.jpg 300w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/Tech-Data-Sheet-768x593.jpg 768w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/Tech-Data-Sheet.jpg 1033w\" sizes=\"(max-width: 640px) 100vw, 640px\" \/><\/a><\/p>\n<h2><strong><em><u>Heat Treatment of Electroless Nickel Plating<\/u><\/em><\/strong><\/h2>\n<p>A common question asked regarding electroless nickel plating is how heat treatment will affect the deposit properties. \u00a0A brief summary of heat treatments are provided below:<\/p>\n<p>Preplate Bakes:\u00a0 Some specifications recommend preplate bakes and\/or shot peening of higher stress ferrous alloys to promote adhesion and reduce the risk of hydrogen em<a href=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignright wp-image-6020\" src=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-3-205x300.png\" alt=\"Medium Phosphorus Electroless Nickel Plating Corrosion Protection\" width=\"267\" height=\"391\" srcset=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-3-205x300.png 205w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-3.png 484w\" sizes=\"(max-width: 267px) 100vw, 267px\" \/><\/a>brittlement.\u00a0 Preplate bakes do not immediately affect the properties of subsequent ENP.<\/p>\n<p>Low Temperature Postplate Bakes (&lt; 500F):\u00a0 These bakes are often used to promote adhesion especially on aluminum alloys and relieve hydrogen embrittlement in ferrous alloys.\u00a0 No appreciable change in deposit properties occur with these lower temperature bakes.<\/p>\n<p>High Temperature Postplate Bakes (500F-750F):\u00a0 These bakes are often used to transition amorphous structure to crystalline structure in both medium and high phosphorus electroless nickel plating.\u00a0 Due to the structure change of the deposit both the hardness increases and corrosion resistance decreases.<\/p>\n<p>Advanced Plating Technologies offers controlled heat treatment of EN\u00a0that reduces or can even fully eliminate cosmetic changes in the appearance of EN deposits (such as darkening) during baking.\u00a0 In addition, APT offers a family of proprietary sealers that can enhance the corrosion protection performance of high-temperature baked electroless nickel deposits to offset and reductions in overall corrosion protection performance.<\/p>\n<h2><strong><em><u>Summary of Electroless Nickel Plating<a href=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-4.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignright wp-image-6021\" src=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-4-200x300.png\" alt=\"High Phosphorus Electroless Nickel Plating Corrosion Protection\" width=\"180\" height=\"270\" srcset=\"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-4-200x300.png 200w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-4-683x1024.png 683w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-4-768x1151.png 768w, https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2016\/06\/corrosion-marked-4.png 830w\" sizes=\"(max-width: 180px) 100vw, 180px\" \/><\/a><\/u><\/em><\/strong><\/h2>\n<p>Electroless nickel plating is engineered finish that can be used to increase the corrosion resistance of various basis metals including cuprous, ferrous and aluminum alloys. The lack of applied current when plating auto-catalytic electroless nickel results in excellent deposit uniformity on even most complex shapes. \u00a0\u00a0In addition to enhancing corrosion protection performance, electroless nickel plating can be used to improve hardness, wear resistance, lubricity, solderability and appearance of components.\u00a0 The phosphorus content of the deposit affects the characteristics of the final finish.\u00a0 Post-plate heat treatments can be used to promote both the adhesion and hardness of electroless nickel plating.<\/p>\n<p>You can find more information on our electroless nickel plating services page as well as <a href=\"https:\/\/advancedplatingtech.com\/contact\/\">contact<\/a> a member of our technical sales staff to discuss your specific application further.\u00a0 Quote requests for electroless nickel plating of any other finish Advanced Plating Technologies offers can be submitted directly through our <a href=\"https:\/\/advancedplatingtech.com\/request-for-quote\/\">RFQ page<\/a>.<\/p>\n<p>&nbsp;<\/p>\n<p><em>Blog authored by Matt Lindstedt, President<\/em><\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Electroless Nickel Plating: Superior Corrosion\u00a0Protection &nbsp; Raw metals other than precious metals can easily oxidize and corrode over time when&hellip;<\/p>\n","protected":false},"author":6,"featured_media":7532,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":false,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2},"_wpas_customize_per_network":false},"categories":[26],"tags":[52],"class_list":["post-3198","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-electroless-nickel","tag-electroless-nickel"],"acf":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/advancedplatingtech.com\/wp-content\/uploads\/2019\/07\/APT-Blog-1.png","jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/p7G6ce-PA","_links":{"self":[{"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/posts\/3198","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/users\/6"}],"replies":[{"embeddable":true,"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/comments?post=3198"}],"version-history":[{"count":0,"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/posts\/3198\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/media\/7532"}],"wp:attachment":[{"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/media?parent=3198"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/categories?post=3198"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/advancedplatingtech.com\/wp-json\/wp\/v2\/tags?post=3198"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}